Aperture 3.4.x: "Open iTunes" button may not work
Resolution
This is a known issue. To work around the issue, open iTunes directly and authorize the computer to play DRM-protected songs purchased with your Apple ID. You can then return to Aperture and select the song to use in your slideshow.
For information on how to authorize a computer to play DRM-protected content, see iTunes Store: About authorization and deauthorization.